Photolabile amphiphiles with fluorogenic thioxanthone-dithiane functionality: synthesis and photoinduced fragmentation in micelles
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چکیده
منابع مشابه
Photolabile Amphiphiles with Fluorogenic Thioxanthone-Dithiane Functionality: Synthesis and Photoinduced Fragmentation in Micelles.
Novel photolabile amphiphiles containing thioxanthone-based fluorogenic caging groups are developed. Photoinduced fragmentation in dithiane-thioxanthone adducts was demonstrated to occur with 100% quantum efficiency at λ ~ 320 nm and more than 50% at λ ~ 360 nm. A plausible mechanism involves homolytic fission of a carbon-carbon single bond in the excited thioxanthone followed by disproportiona...
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ژورنال
عنوان ژورنال: Journal of Sulfur Chemistry
سال: 2008
ISSN: 1741-5993,1741-6000
DOI: 10.1080/17415990802027289